{"version":"1.0","provider_name":"In Abstract","provider_url":"https:\/\/www.mub.eps.manchester.ac.uk\/in-abstract","author_name":"Enna Bartlett","author_url":"https:\/\/www.mub.eps.manchester.ac.uk\/in-abstract\/author\/ennabartlett\/","title":"Controlling Reactivity by Geometry in Retro-Diels-Alder Reactions under Tension - In Abstract","type":"rich","width":600,"height":338,"html":"<blockquote class=\"wp-embedded-content\" data-secret=\"iTSGYftqo1\"><a href=\"https:\/\/www.mub.eps.manchester.ac.uk\/in-abstract\/controlling-reactivity-by-geometry\/\">Controlling Reactivity by Geometry in Retro-Diels-Alder Reactions under Tension<\/a><\/blockquote><iframe sandbox=\"allow-scripts\" security=\"restricted\" src=\"https:\/\/www.mub.eps.manchester.ac.uk\/in-abstract\/controlling-reactivity-by-geometry\/embed\/#?secret=iTSGYftqo1\" width=\"600\" height=\"338\" title=\"&#8220;Controlling Reactivity by Geometry in Retro-Diels-Alder Reactions under Tension&#8221; &#8212; In Abstract\" data-secret=\"iTSGYftqo1\" frameborder=\"0\" marginwidth=\"0\" marginheight=\"0\" scrolling=\"no\" class=\"wp-embedded-content\"><\/iframe><script type=\"text\/javascript\">\n\/* <![CDATA[ *\/\n\/*! This file is auto-generated *\/\n!function(d,l){\"use strict\";l.querySelector&&d.addEventListener&&\"undefined\"!=typeof URL&&(d.wp=d.wp||{},d.wp.receiveEmbedMessage||(d.wp.receiveEmbedMessage=function(e){var t=e.data;if((t||t.secret||t.message||t.value)&&!\/[^a-zA-Z0-9]\/.test(t.secret)){for(var s,r,n,a=l.querySelectorAll('iframe[data-secret=\"'+t.secret+'\"]'),o=l.querySelectorAll('blockquote[data-secret=\"'+t.secret+'\"]'),c=new RegExp(\"^https?:$\",\"i\"),i=0;i<o.length;i++)o[i].style.display=\"none\";for(i=0;i<a.length;i++)s=a[i],e.source===s.contentWindow&&(s.removeAttribute(\"style\"),\"height\"===t.message?(1e3<(r=parseInt(t.value,10))?r=1e3:~~r<200&&(r=200),s.height=r):\"link\"===t.message&&(r=new URL(s.getAttribute(\"src\")),n=new URL(t.value),c.test(n.protocol))&&n.host===r.host&&l.activeElement===s&&(d.top.location.href=t.value))}},d.addEventListener(\"message\",d.wp.receiveEmbedMessage,!1),l.addEventListener(\"DOMContentLoaded\",function(){for(var e,t,s=l.querySelectorAll(\"iframe.wp-embedded-content\"),r=0;r<s.length;r++)(t=(e=s[r]).getAttribute(\"data-secret\"))||(t=Math.random().toString(36).substring(2,12),e.src+=\"#?secret=\"+t,e.setAttribute(\"data-secret\",t)),e.contentWindow.postMessage({message:\"ready\",secret:t},\"*\")},!1)))}(window,document);\n\/* ]]> *\/\n<\/script>\n","thumbnail_url":"https:\/\/www.mub.eps.manchester.ac.uk\/in-abstract\/wp-content\/uploads\/sites\/61\/2018\/03\/Controlling-Reactivity-by-Geometry-in-Retro-Diels-Alder-Reactions-under-Tension.jpg","thumbnail_width":890,"thumbnail_height":350,"description":"A molecular tug-of-war Mechanical force, with its ability to distort, \u2028bend, and stretch chemical bonds, is unique in the way it\u2028 activates chemical reactions. Now, researchers at the University of Manchester have shown that mechanical force can enhance or suppress the ability of polycyclic adducts to disassemble, in a process known as a retro-Diels-Alder reaction, [&hellip;]"}